Polymerization

Definition

polymer is a substance made up of many repeating units (called monomer units). Polymers are usually distinguished by a high molar mass (formula weight), often ranging into thousands or millions of grams per formula unit.

Polymerization is the process by which monomers (smaller chemical units) are combined to form a polymer. Polymerization is a poly-reaction of a monomer compound which molecule contains double bondings or rings The poly-reaction can occure under following conditions:

Triggered by

The polymerization can be triggered by the following factors

  • Initiator (reaction partner)
  • Heat
  • Light
  • Radiation

Some unsaturated compounds with one or more double bonds are able to polymerise.

  • Vinyl compounds
  • Vinylidene compounds
  • Acrylic compounds
  • Carbonyl compounds
  • Styrene
  • Ethylene Oxide; Propylene Oxide
  • Ethylene, Propylene, Isobutylene, Butadiene and Isoprene

Example

Ethylene (C2H4) is a highly flammable gaseous molecule with a formula weight (molar mass) of 32 grams per mol. When polymerized using a catalyst, it forms an insoluble solid comprised of straight chains of CH2 units called polyethylene. Polyethylene is a widely used commodity plastic.

Polymerization reaction